Detailed Project Report (DPR) on bromine recovery plant

Detailed Project Report (DPR) on bromine recovery plant
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India
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Industry Overview

Bromine is a deep red, fuming liquid and the only non-metallic element that is liquid at normal temperature. It belongs to Group VII of the periodic table and occurs naturally in the combined state as bromides, particularly in seawater, brines, salt lakes, saline deposits, and bitterns remaining after salt crystallization. Commercial bromine production has traditionally relied on saline mother liquors and later expanded to seawater and other concentrated brine sources.

Bromine was discovered in the early 19th century and initially gained importance through bromide applications in medicine. Its industrial significance increased substantially with the development of photographic processes using silver bromide. Bromine is also widely used in chemical and pharmaceutical industries, including flame retardants, pesticides, reactive intermediates, and pharmaceutical ingredients.

Industrial recovery commonly involves oxidation of bromide using chlorine, followed by separation, purification, and drying. Bromine recovery from industrial streams can also be economically viable because bromination reactions may generate hydrogen bromide and dissolved bromides as by-products. The report identifies seawater, brines, bitterns, and natural potassium salt deposits as important sources and discusses both hot steaming-out and cold air-blowing recovery processes.

Because bromine is highly corrosive and toxic, bromine plants require corrosion- and diffusion-resistant construction materials, secure containment, appropriate pressure and flange-tightness provisions, and bromine scrubbers in vent systems.

Cost Estimation

Particulars Value
Plant Capacity 6 MT/Day
Land & Building (8000 sq.mt.) Rs. 4.04 Cr
Plant & Machinery Rs. 3.50 Cr
Working Capital for 1 Month Rs. 2.59 Cr
Total Capital Investment Rs. 10.45 Cr
Rate of Return 44%
Break Even Point 50%

Content Index

  • INTRODUCTION
  • USES, SOURCE AND SAFETY OF BROMINE
  • USE OF BROMINE
  • SOURCES OF BROMINE
  • SAFETY FIRST
  • ORIGIN OF BROMINE
  • PROPERTIES
  • USES & APPLICATION
  • SOURCES OF BROMINE
  • SOURCES OF BROMINE
  • MARKET OVERVIEW OF BROMINE
  • MAJOR BROMINE MANUFACTURING COUNTRIES
  • INCREASING DEMAND FOR FLAME RETARDANTS
  • CHINA TO DOMINATE THE ASIA-PACIFIC MARKET
  • MAJOR PLAYERS
  • RAW MATERIAL SECTION
  • MATERIALS OF CONSTRUCTION FOR CHLORINE HANDLING:-
  • B.I.S. SPECIFICATIONS
  • SCOPE:-
  • REQUIREMENTS:-
  • TABLE - 1: REQUIREMENTS FOR BROMINE, TECHNICAL
  • PACKING & MARKETING:-
  • PACKING:-
  • MARKING:-
  • SAMPLING:-
  • ANALYSIS OF BROMINE, TECHNICAL
  • DETERMINATION OF BROMINE:-
  • PROCEDURE:-
  • DETERMINATION OF CHLORINE:-
  • PROCEDURE:-
  • DETERMINATION OF NON-VOLATILE MATTER:-
  • TEST FOR IODINE:-
  • ZINC DUST:-
  • TEST FOR SULPHATES:-
  • PROCEDURE:-
  • SAMPLING OF BROMINE, TECHNICAL
  • NUMBER OF CONTAINERS TO BE DRAWN FOR SAMPLING
  • LOCATION OF THE PLANT
  • HEALTH & SAFETY FACTORS
  • MANUFACTURING PROCESS OF BROMINE
  • BROMINE GENERATION
  • BROMINE SEPARATION
  • PURIFICAION AND DRYING
  • PROCESS FLOW DIAGRAM
  • BROMINE RECOVERY PLANT
  • BROMINE CAN BE RECOVERED FROM TWO SOURCES
  • A) STEAMING OUT PROCESS (HOT PROCESS)
  • B) AIR BLOWING PROCESS (COLD PROCESS)
  • BROMINE PROCESSES
  • PRODUCTION OF BROMINE
  • PROCESSING DETAILS OF BROMINE RECOVERY
  • PROCESS FLOW DIAGRAM
  • INDUSTRIAL PRODUCTION OF BROMINE
  • THE BROMINE-GENERATING STEP
  • RESIDUAL ORGANIC MATTER FOUND IN DEAD SEA WATER
  • SIDE-REACTIONS OCCURRING IN THE REACTION TOWER
  • BROMINE SEPARATION STEPS
  • 1. CONDENSATION
  • 2. SEPARATION
  • 3. PURIFICATION
  • MANUFACTURE OF LIQUID BROMINE
  • PROCESS
  • THE FOUR PRINCIPAL STEPS IN BROMINE PRODUCTION ARE
  • STEAMING OUT PROCESS:-
  • DOW PROCESS:-
  • CONSTRUCTION MATERIAL OF BROMINE PLANT
  • SAFE HANDLING OF BROMINE LEAKAGE
  • SAFE STORAGE OF BROMINE
  • STORAGE AND TRANSPORTTATION HAZARDS OF BROMINE
  • HAZARDS OF BROMINE
  • • A CORROSIVE SUBSTANCE:
  • • TOXIC:
  • SUPPLIERS OF RAW MATERIALS
  • SUPPLIERS OF PLANT AND MACHINERY
  • SUPPLIERS OF HEAT EXCHANGER
  • SUPPLIERS OF CONDENSER
  • SUPPLIERS OF DISTILLATION COLUMN
  • SUPPLIERS OF STORAGE VESSEL (STORAGE TANKS)
  • SUPPLIERS OF LABORATORY EQUIPMENTS
  • SUPPLIERS OF D.G. SETS
  • SUPPLIERS OF BOILERS
  • SUPPLIERS OF EFFULENT TREATMENT PLANT (ETP PLANT)
  • SUPPLIERS OF INSTRUMENTATION & PROCESS CONTROL EQUIPMENTS
  • GOVT. LICENSE DETAILS FOR LIQUID BROMINE PLANT

Appendix

  • APPENDIX – A:
  • 01. PLANT ECONOMICS
  • 02. LAND & BUILDING
  • 03. PLANT AND MACHINERY
  • 04. OTHER FIXED ASSESTS
  • 05. FIXED CAPITAL
  • 06. RAW MATERIAL
  • 07. SALARY AND WAGES
  • 08. UTILITIES AND OVERHEADS
  • 09. TOTAL WORKING CAPITAL
  • 10. TOTAL CAPITAL INVESTMENT
  • 11. COST OF PRODUCTION
  • 12. TURN OVER/ANNUM
  • 13. BREAK EVEN POINT
  • 14. RESOURCES FOR FINANCE
  • 15. INSTALMENT PAYABLE IN 5 YEARS
  • 16. DEPRECIATION CHART FOR 5 YEARS
  • 17. PROFIT ANALYSIS FOR 5 YEARS
  • 18. PROJECTED BALANCE SHEET FOR (5 YEARS)

Frequently Asked Questions

The main sources of bromine are seawater, brines, bitterns, salt lakes, and natural deposits of potassium salts. Bromine occurs naturally in these sources in the combined state as bromides. Sea bitterns, which remain after salt crystallization, can be particularly rich in bromine and are suitable raw materials for recovery. The report also identifies industrial quench waters and effluents from bromination processes as potential sources for bromine recovery.

Bromine is widely used in chemical and pharmaceutical applications, particularly in brominated organic compounds. Important applications described in the report include flame retardants, pesticides such as methyl bromide, reactive intermediates used in organic synthesis, and pharmaceutical ingredients. Bromine compounds have also historically been important in photographic processes because silver bromide is light-sensitive. The report notes that bromide applications in medicine were among the earlier uses of bromine compounds.

Industrial bromine production generally involves recovering bromine from bromide-containing seawater, brines, bitterns, or other saline streams through chemical oxidation and subsequent separation. The report describes bromine generation, bromine separation, purification, and drying as key process stages. It also discusses steaming-out, or hot-process recovery, and air blowing, or cold-process recovery, along with condensation, separation, and purification steps used in the manufacture of liquid bromine.

Bromine recovery from industrial streams can be economically viable because bromination reactions may generate hydrogen bromide and dissolved bromides as by-products. The report notes that not all bromine added during certain reactions becomes part of the desired product, with some released as hydrogen bromide gas or remaining as dissolved bromides in washing solutions. Recovering this bromine can reduce raw-material losses and provide an opportunity to reuse a valuable chemical feedstock.

A bromine plant requires stringent containment, corrosion resistance, leak prevention, and ventilation controls because bromine is highly corrosive and toxic. The report recommends robust, corrosion- and diffusion-resistant construction materials, including QVF borosilicate glass 3.3 and glass-lined steel. Equipment should meet appropriate pressure and flange-tightness requirements, while vent systems should be equipped with bromine scrubbers. Safe handling, storage, transportation, and leakage-control procedures are also essential parts of plant safety.

Corrosion- and diffusion-resistant materials are required for bromine processing equipment. The report specifically identifies QVF borosilicate glass 3.3 and glass-lined steel as ideal materials for plant construction. Material selection is important because bromine can cause serious corrosion and chemical damage. The overall plant design should also address pressure containment, tight flange connections, leakage prevention, and controlled venting through suitable scrubbing systems.

The principal steps in bromine recovery are bromine generation, separation, purification, and drying. Depending on the selected recovery technology, bromine can be recovered through a steaming-out process or an air-blowing process. The report further describes condensation, separation, and purification within the bromine separation stage. Process selection depends on the bromide-containing source, operating conditions, equipment design, and the desired quality of the recovered bromine.

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