Aluminium sulfate (Al2(SO4)3), commonly known as alum, is a water-soluble, non-combustible material produced in crystalline, solid, and solution forms. The dry hydrate, Al2(SO4)3.14H2O, contains 17% Al2O3, while aluminium sulfate is also marketed as a 47% w/w solution containing 8% Al2O3. Solid alum is supplied in kibbled, ground, dust, lump, and other commercial forms.
Ferric and non-ferric alum are available in various grades. Ferric alum is generally produced from bauxite and contains iron, whereas non-ferric alum is generally produced from alumina. Historically, alum was prepared from alum shales by roasting and leaching. Potash alum has also been produced by crystallizing equivalent proportions of potassium sulfate and aluminium sulfate, followed by concentration and separation of crystals.
The principal application of alum is water treatment and clarification, where hydrolysis produces aluminium hydroxide that helps remove colloidal impurities. Another major application is paper sizing, where alum reacts with sodium resinate to form insoluble aluminium resinate and improve resistance to liquid penetration. Alum is also used in dyes, food, petroleum, pharmaceuticals, fire-proofing, tanning, and other industrial applications. Technical-grade aluminium sulfate is supplied as partially dehydrated solid and aqueous solution, while reagent-grade material is available as colourless crystals.
| Particulars | Value |
|---|---|
| Plant Capacity | 20 MT./Day |
| Land & Building (2000 sq.mt.) | Rs. 76 Lacs |
| Plant & Machinery | Rs. 93 Lac |
| Working Capital for 1 Month | Rs. 70 Lac |
| Total Capital Investment | Rs. 2.51 Cr |
| Rate of Return | 24% |
| Break Even Point | 73% |
Aluminium sulfate, commonly called alum, is a water-soluble aluminium salt used extensively in industrial applications. It is produced in crystalline, partially dehydrated solid, and aqueous solution forms. The report identifies ferric and non-ferric alum as two broad categories, with ferric alum generally made from bauxite and non-ferric alum generally made from alumina. Commercial material is supplied under several names and in forms such as lumps, granules, powder, flakes, kibbled material, and liquid solution.
The main uses of alum are water treatment and paper sizing. In water treatment, alum assists clarification by forming aluminium hydroxide through hydrolysis, which helps carry colloidal impurities into a removable sludge layer. In paper manufacturing, alum reacts with sodium resinate to form insoluble aluminium resinate and contributes to resistance against liquid penetration. The report also identifies applications in dyes, food, petroleum, pharmaceuticals, fire-proofing, tanning, and other industries.
Ferric alum contains iron, whereas non-ferric alum is intended to be substantially free from ferric ions. The report states that ferric alum is generally produced from bauxite and non-ferric alum is generally produced from alumina. This distinction is important for applications where iron impurities can affect product colour or performance, particularly paper sizing. The two product categories can therefore require different raw materials, specifications, quality-control procedures, and process considerations.
Alum is primarily used as a coagulant to assist the clarification of water. When aluminium sulfate hydrolyses, aluminium hydroxide is formed and helps capture colloidal and suspended impurities, allowing them to be separated during subsequent treatment. A conventional water-treatment process can include screening, pre-sedimentation, chemical pretreatment, coagulation and flocculation, sedimentation, filtration, and disinfection. The appropriate treatment sequence depends on the characteristics of the source water and the required finished-water quality.
The report identifies bauxite as a principal raw material for ferric alum and alumina as a principal raw material for non-ferric aluminium sulfate. It also contains sections covering sulphuric acid and other raw-material requirements and suppliers. The precise raw-material combination depends on the selected manufacturing route, product grade, required aluminium content, and impurity limits. Industrial production therefore requires controlled raw-material quality together with suitable reaction, concentration, crystallization, and finishing operations.
Quality testing for non-ferric aluminium sulfate can include checks for insoluble matter, pH, heavy metals, iron, chlorides, arsenic, ammonium salts, aluminium, sodium, and potassium. The report includes detailed sections on reagent quality, sample preparation, analytical procedures, apparatus, standard solutions, calculations, sampling, number of tests, and conformity criteria. Such testing helps verify that the finished alum meets its specified chemical and physical requirements and is suitable for its intended industrial application.
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